Mapping IMDG classes to UN classes
When dangerous goods move by sea they are regulated by the IMO’s IMDG Code, but the hazard classes themselves come from the United Nations dangerous goods system. This reference cross-references each IMDG class and division to its UN class number, with the hazard name and example substances, so you can confirm the class for a cargo or read a shipping document.
How it works
The key fact is that the class numbers are shared:
IMDG Class 3 == UN Class 3 (flammable liquids)
IMDG Class 4.3 == UN Class 4 (dangerous when wet)
IMDG Class 8 == UN Class 8 (corrosives)
The IMO adopted the UN class scheme, so there is no renumbering between the two; the class digit is identical. What the IMDG Code adds on top is maritime detail: the explosive divisions 1.1 to 1.6, packing groups I to III for the degree of danger, and segregation tables saying which classes must be stowed apart on board. Divisions such as 2.1, 2.2, 2.3 or 4.1, 4.2, 4.3 refine the broad class into specific hazards.
Tips and notes
The older abbreviation IMCO refers to the former name of the IMO and describes the same class scheme, so an IMCO class label is just an IMDG class. For a given substance the authoritative source is its UN number and proper shipping name in the dangerous goods list, which fixes the class, division, and packing group together. Marine pollutants and lithium batteries both fall under the catch-all Class 9.